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The solution to this problem is in two parts: Alkyl substituents in the benzene nuclei evidently require a higher fission energy since they are not detached under the given thermal conditions. 4-tert-butylphenol and a technical xylenol fraction were studied. This relation is manifest since comparison of the commencements o f TFG-zones w ith the boiling points o f the plasticisers under reduced pressure shows the same tendency. extends group classification o f the various ester types to these miss­ ing phosphates and sulfonates. see Table 25 Scheme 8.

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